Is it best to use this in the AM, or can I make it a part of my PM routine?

Exfoliants are ideally used only at night since they will make your skin more sun sensitive and more likely to burn/tan, aka damage your skin. Use at night after cleansing and before serums!

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Glossier
Solution Skin-Perfecting Daily Chemical Exfoliator

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Glossier
Solution Skin-Perfecting Daily Chemical Exfoliator